calories (cal) to British Thermal Units (IT) (BTU) conversion

What is calories?

Calories are a unit of energy, historically defined as the amount of heat required to raise the temperature of one gram of water by one degree Celsius. While the "calorie" is still commonly used, the kilocalorie (kcal), also known as the "large calorie" or "food calorie," is more prevalent when discussing dietary energy. In the International System of Units (SI), the joule (J) is the standard unit of energy.

Types of Calories

• Small calorie (cal): The amount of energy required to raise the temperature of 1 gram of water by 1°C.
• Large calorie (Cal) or Kilocalorie (kcal): The amount of energy required to raise the temperature of 1 kilogram of water by 1°C. This is the calorie commonly referred to in nutrition.

The relationship between these units is:

$1 \text{ Cal} = 1 \text{ kcal} = 1000 \text{ cal}$

Calorie to Joule Conversion

Since the joule is the SI unit for energy, it's useful to know the conversion factor:

$1 \text{ cal} \approx 4.184 \text{ J}$

$1 \text{ kcal} \approx 4184 \text{ J}$

Historical Context

While not directly related to a specific law, the development of calorimetry (the science of measuring heat) was crucial to understanding calories. Scientists like Nicolas Clément and later Wilbur Olin Atwater, a pioneer in nutrition science, contributed significantly to establishing calorie values for different foods. Atwater's work in the late 19th and early 20th centuries was instrumental in developing the calorie system used in nutrition today.

Real-World Examples and Calorie Values

• Food:

  • One medium apple (approx. 182g): ~95 kcal
  • One slice of whole wheat bread: ~70 kcal
  • A can of soda (355ml): ~150 kcal

• Energy Expenditure:

  • A 150-pound person running for 30 minutes at 6 mph burns approximately 340 kcal.
  • Sleeping for 8 hours burns roughly 50 kcal per hour, totaling around 400 kcal.

• Other Quantities:

  • Gasoline: 1 gallon of gasoline contains approximately 31,000 kcal.

Measuring Calories in Food

Calories in food are typically determined using a bomb calorimeter. This device measures the heat released when a food sample is completely burned inside a closed chamber surrounded by water. The temperature increase of the water is then used to calculate the calorie content of the food. The caloric content in the three macronutrients are as follows:

• Carbohydrates: 4 kcal/gram
• Proteins: 4 kcal/gram
• Fats: 9 kcal/gram

What is the British Thermal Unit (IT)?

The British thermal unit (IT) is a unit of energy in the imperial and US customary systems, defined as roughly the heat needed to raise the temperature of one pound of water by one degree Fahrenheit. It is widely used in heating, cooling, and the power industries.

Definition

The "IT" (International Steam Table) British thermal unit is defined exactly in terms of the SI joule.

$$1\ \text{BTU} = 1055.06\ \text{J}$$

The exact value is 1 BTU (IT) = 1055.05585262 J. This IT definition is fixed by convention (derived from 1 BTU_IT = 1055.05585262 J, i.e. based on the International Steam Table calorie of 4.1868 J). It differs slightly from the thermochemical BTU (1054.35 J) and the mean BTU, because the amount of heat to warm water depends on the starting temperature.

Origin and History

The BTU arose in the 19th century alongside the calorie as engineers sought a practical unit tied to water and everyday temperature scales. Multiple definitions emerged (39 °F, 60 °F, mean, thermochemical), and the International Steam Table conference of 1956 fixed the IT calorie, and hence the IT BTU, to a precise joule value.

Law and Notable Facts

In the United States, air conditioners and furnaces are rated in BTU per hour, and natural gas is sold in therms (1 therm = 100,000 BTU). One "ton" of cooling equals 12,000 BTU/h, historically the heat absorbed by melting one short ton of ice in 24 hours.

Real-World Examples and Conversions

• 1 BTU ≈ 1055 J ≈ 0.293071 watt-hour; a 5000 BTU/h window air conditioner draws about 1465 W of cooling.
• 1 BTU is roughly the energy released by burning one wooden match.
• 1 kWh = 3412.14 BTU, and 1 therm = 105.506 MJ.